Reducing or avoiding surface irregularities in...

C - Chemistry – Metallurgy – 25 – D

Patent

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C25D 13/20 (2006.01) C23C 22/83 (2006.01)

Patent

CA 2213824

The phenomenon of "mapping" (surface defects) after electrophoretic painting over phosphate conversion coatings passivated with hexavalent chromium containing passivating compositions can be avoided or reduced by keeping the surface being treated constantly wet from the time it is conversion coated until it is electrophoretically painted, by preceding the passivating step by treatment with an aqueous liquid treatment composition comprising at least one of the following components; (A) a water soluble and/or water dispersible polymer with a weight average molecular weight of at least 500; (B) fluorometallic acids and anions thereof, the molecules of which consist of (i) at least one atom of boron, silicon, zirconium, iron, aluminum, or titanium, (ii) at least four fluorine atoms, and, optionally, (iii) one or more atoms of oxygen, hydrogen, or both; (C) zirconium salts of ethylenediamine acid; and (D) alkali metal and ammonium zirconyl carboxylates and carbonates; or by replacing the chromium containing passivating composition with an aqueous liquid treatment composition of the same type as described above.

Les défauts de surface apparaissant après une peinture par électrophorèse sur des surfaces passivées par phosphatage à l'aide de produits passivants à base de chrome hexavalent peuvent être supprimés ou atténués en maintenant la surface dans une humidité permanente entre son revêtement par conversion et l'application de la peinture par électrophorèse. Cela s'obtient en faisant précéder l'étape de passivation par un traitement à l'aide d'une composition liquide aqueuse comportant au moins les constituants suivants: (A) un polymère hydrosoluble ou hydrodispersible d'un poids moléculaire moyen d'au moins 500; (B) des acides fluorométalliques ou leurs anions dont les molécules comportent (i) un atome de bore, de silicium, de zirconium de fer, d'aluminium ou de titane, (ii) au moins quatre atomes de fluor, et (iii) facultativement un ou plusieurs atomes d'oxygène, d'hydrogène ou des deux; (C) des sels de zirconium de l'acide éthylènediaminetétraacétique; et (D) des zirconylcarboxylates ou carbonates d'ammonium ou de métaux alcalins; ou en remplaçant la composition passivante contenant du chrome par une composition liquide aqueuse de traitement du type décrit ci-dessus.

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