Reforming process using high density catalyst

B - Operations – Transporting – 01 – J

Patent

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B01J 23/62 (2006.01) B01J 35/00 (2006.01) C10G 35/09 (2006.01)

Patent

CA 2586727

A catalyst and a process for using the catalyst are disclosed generally for the conversion of hydrocarbons. The catalyst has an increased average bulk density and a decreased mass ratio of platinum-group metal. The process using the catalyst obtains unexpected high activity and stability for the reforming of naphtha range hydrocarbons. Mössbauer spectroscopy is used to characterize the extent of tin association with platinum and determine an effective molar tin ratio appropriate for alumina supports with densities above 0.6 g/cc.

La présente invention décrit un catalyseur et un procédé utilisant le catalyseur qui servent habituellement à la conversion d~hydrocarbures. Le catalyseur possède une densité apparente moyenne accrue et un rapport de masse réduit du métal du groupe platine. Le procédé faisant appel à ce catalyseur donne une activité et une stabilité élevées inattendues pour le reformage d~hydrocarbures de type naphta. Une spectroscopie Mössbauer est utilisée pour caractériser le degré d~association de l~étain avec le platine et déterminer un rapport molaire efficace d~étain approprié pour des supports en alumine avec des densités supérieures à 0,6 g/ml.

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