Regiospecific synthesis of anthracyclinone compounds such as...

Details Regiospecific synthesis of anthracyclinone compounds such as... Regiospecific synthesis of anthracyclinone compounds such as...

C - Chemistry, Metallurgy

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C

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C07C 50/38 (2006.01) C07C 43/225 (2006.01) C07C 43/23 (2006.01) C07C 45/46 (2006.01) C07C 45/58 (2006.01) C07C 45/59 (2006.01) C07C 45/63 (2006.01) C07C 205/57 (2006.01) C07D 303/22 (2006.01) C07H 15/24 (2006.01)

Patent

CA 1179331

BFN 7097 ABSTRACT A regiospecific synthesis for anthracyclinones asymmetric is disclosed. The synthesis is based upon a regiospecific bromination of the C-7 position of the .alpha. -tetralone which after transposing the keto group to the .beta.-position and reaction with an organo-lithium compound is condensed with a phthalate ester.

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