Removal of thorium from raffinate

C - Chemistry – Metallurgy – 22 – B

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C22B 3/38 (2006.01) C22B 60/02 (2006.01)

Patent

CA 2007109

Thorium is removed from raffinate effluent by pre-washing with odourless kerosene to remove organic contaminants, followed by solvent extraction counter-currently with tri-n-octylphosphine oxide in odourless kerosene. The loaded solvent from the solvent extraction is back-washed with K2CO3 solution at about 60°C, and subsequent lime addition precipitates Th(OH)4.

Le thorium est éliminé dans l'effluent d'un raffinat par pré-lavage avec du kérosène inodore pour séparer les contaminants organiques, suivi d'une extraction à contre-courant à l'aide d'un solvant à l'oxyde de tri-n-octylphosphine dans du kérosène inodore. Après extraction, le solvant chargé est lavé par retour d'une solution de K2CO3 à 60 degrés C environ; l'addition ultérieure de chaux précipite le Th(OH)4.

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