Resolution of chiral compounds using aminocyclopentadienyl...

Details Resolution of chiral compounds using aminocyclopentadienyl... Resolution of chiral compounds using aminocyclopentadienyl...

C - Chemistry, Metallurgy

07

C

C07C 67/42 (2006.01) C07C 29/00 (2006.01) C07C 29/56 (2006.01) C07F 15/00 (2006.01) C12P 7/24 (2006.01) C12P 41/00 (2006.01)

Patent

CA 2478408

A chiral compound, particularly a chiral secondary alcohol, can be efficiently resolved under a mild condition by acylation with an alkenyl acetate in the presence of a novel aminocyclopentadienyl ruthenium complex, an enzyme catalyst, and a base.

Un composé chiral, en particulier un alcool chiral secondaire, peut être résolu efficacement dans des conditions douces par acylation avec un alcényle acétate en la présence d'un nouveau complexe d'aminocyclopentadiényle ruthénium, d'un catalyseur enzymatique et d'une base.

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