Reversible electrode material

H - Electricity – 01 – M

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H01M 4/60 (2006.01) H01M 10/40 (2006.01)

Patent

CA 2060127

The present invention provides an electrode material comprising a combination of a compound having a disulfide group and a conductive polymer, or a con- ductive polymer having a disulfide group, wherein an S-S bond of the disulfide group is cleaved by the electrolytic reduction to form a sulfur-metal ion bond or a sulfur-proton bond, and the sulfur-metal ion bond or the sulfur-proton bond re-forms an S-S bond by the electrolytic oxidation. The present invention also provides a lithium rechargeable battery comprising a cathode, a solid electrolyte, and an anode, wherein the cathode is made of a composition containing as its main components lithium thiolate having a sulfur-lithium ion bond capable of forming a disulfide bond by the elec- trolytic oxidation and a .pi. electron conjugated conduc- tive polymer; or a composition containing as its main component a .pi. electron conjugated conductive polymer having a sulfur-lithium ion bond capable of forming a disulfide bond by electrolytic oxidation; the solid electrolyte is a composition containing a salt contain- ing lithium, or a polymer containing the salt; and the anode is made of a composition containing as its main components aluminium or an alloy containing aluminium, and carbon.

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