Rubbery polymer

C - Chemistry – Metallurgy – 08 – F

Patent

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Details

C08F 220/16 (2006.01) C08F 2/22 (2006.01) C08F 2/26 (2006.01) C08F 6/14 (2006.01) C08F 8/32 (2006.01) C08F 212/08 (2006.01) C08F 220/18 (2006.01) C08F 265/04 (2006.01) C08F 265/06 (2006.01) C08K 3/26 (2006.01) C08K 3/36 (2006.01) C08L 27/06 (2006.01) C08L 33/08 (2006.01) C08L 51/06 (2006.01)

Patent

CA 2171390

There is a need for polymers which are utilized in automotive interiors which offer increased heat and ultraviolet light resistance. It is particularly critical for polymers which are utilized in making skin compounds for automotive instrument and door panels to display excellent heat and ultraviolet light resistance. This invention discloses a process for preparing a rubbery polymer which can be blended with polyvinyl chloride to make leathery compositions having good heat and ultraviolet light resistance, said process comprising the steps of (1) polymerizing (a) butyl acrylate, (b) at least one member selected from the group consisting of methyl methacrylate, ethyl methacrylate, methyl acrylate, and ethyl acrylate, (c) acrylonitrile, (d) a crosslinking agent, and (e) a half ester maleate soap under emulsion polymerization conditions to produce a seed polymer containing latex; (2) adding (a) styrene, (b) additional acrylonitrile, and (c) additional crosslinking agent to the seed polymer containing latex under emulsion polymerization conditions which result in the formation of an emulsion containing the rubbery polymer; (3) adding an aminoalcohol to the emulsion containing the rubbery polymer; and (4) recovering the rubbery polymer from the emulsion containing the rubbery polymer.

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