Ruthenium catalyzed process for preparation of...

Details Ruthenium catalyzed process for preparation of... Ruthenium catalyzed process for preparation of...

C - Chemistry, Metallurgy

07

F

C07F 7/10 (2006.01) B01J 31/24 (2006.01) C07F 7/14 (2006.01)

Patent

CA 2114586

RUTHENIUM CATALYZED PROCESS FOR PREPARATION OF .beta.-CYANOALKYLSILANES ABSTRACT The present invention is a process for the preparation of hydrolyzable .beta.-cyanoalkylsilanes. More particularly, this invention relates to the catalytic addition of trichlorosilane to .alpha.,.beta.-unsaturated olefinic nitriles to form .beta.-cyanoalkylsilanes. The present process employs a catalyst comprising a ruthenium compound. The preferred catalyst for the present process is a ruthenium compound having at least one tertiary phosphine ligand. The process is conducted at a temperature within a range of 50°C. to 300°C.

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