Ruthenium hydrogenation catalysts

Details Ruthenium hydrogenation catalysts Ruthenium hydrogenation catalysts

C - Chemistry, Metallurgy

07

F

C07F 15/00 (2006.01) B01J 31/24 (2006.01) C07C 29/149 (2006.01) C07C 209/32 (2006.01) C07C 209/36 (2006.01) C07C 209/48 (2006.01) C07C 213/02 (2006.01) C07C 249/02 (2006.01) C07C 251/02 (2006.01) C07C 253/30 (2006.01) C07C 255/61 (2006.01) C07D 213/38 (2006.01) C07D 307/52 (2006.01)

Patent

CA 2209379

The invention relates to a novel ruthenium complex having the formula Ru(3- C6H8-PCy2)(PCy3)Cl, wherein Cy is cyclohexyl; its use in the preparation of RuHCl(H2)(PCy3)2 and RuH2(H2)2(PCy3)2; and the use of the complexes as catalysts in hydrogenation, imination and reductive hydrolysis processes.

L'invention porte sur un nouveau complexe de ruthénium de la formule Ru(??3¿-C¿6?H¿8?-PCy¿2?)(PCy¿3?)Cl, dans laquelle Cy est cyclohéxyle. Ledit complexe sert à la préparation de RuHCl(H¿2?)(PCy¿3?)¿2? et de RuH¿2?(H¿2?)¿2?(PCy¿3?)¿2?. L'invention porte en outre sur l'utilisation de ce complexe comme catalyseur dans des processus d'hydrogénation, d'imination et d'hydrolyse réductrice.

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