Selective carboxylation process

C - Chemistry – Metallurgy – 07 – C

Patent

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C07C 51/14 (2006.01) B01J 31/16 (2006.01) B01J 31/18 (2006.01) B01J 31/24 (2006.01) C07C 67/38 (2006.01)

Patent

CA 1067511

ABSTRACT This invention relates to a process for selectively carboxylating alpha (.alpha.) olefins present in a mixture of .alpha. -olefins and internal olefins by contacting said olefin mixture with carbon monoxide and hydroxyl-containing reactants, in the presence of an empirically derived class of three (3) component catalysts consisting of ligand stabilized, platinum(II) dihalide complexes in combination with Group IVB metal halides. I

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