Selective catalytic oxidation of unsaturated alcohols to...

Details Selective catalytic oxidation of unsaturated alcohols to... Selective catalytic oxidation of unsaturated alcohols to...

C - Chemistry, Metallurgy

07

C

260/518, 260/583

C07C 45/26 (2006.01) B01J 23/58 (2006.01) C07C 45/30 (2006.01) C07C 51/16 (2006.01) C07C 51/25 (2006.01) C07C 51/29 (2006.01) C07C 61/04 (2006.01)

Patent

CA 1072577

Abstract Primary and secondary unsaturated alcohols are converted to their corresponding aldehydes and/or carboxylic acids and ketones respectively with alkali metal (per) halate, preferably sodium periodate, in the presence of ruthenium catalyst. The process is particularly useful in the oxidation of chrysanthemyl alcohol. Any unconverted intermediate aldehyde formed may be converted to the acid by recycling or by a separate oxidation step.

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