Selective formation of ethanol from methanol, hydrogen and...

C - Chemistry – Metallurgy – 07 – C

Patent

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260/639

C07C 31/08 (2006.01)

Patent

CA 1107765

SELECTIVE FORMATION OF ETHANOL FROM METHANOL, HYDROGEN AND CARBON MONOXIDE ABSTRACT A process for the selective formation of ethanol which comprises contacting methanol, hydrogen and carbon monoxide with a catalyst system comprising a source of cobalt, which under the reaction conditions will generate a hydrido cobalt carbonyl complex, such as cobalt acetylacetonate, a tertiary organo Group V A compound of the periodic table, a first promoter comprising an iodine compound and a second promoter comprising a ruthenium compound.

319032

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