Selective hydrocarboxylation of propylene to isobutyric acid

C - Chemistry – Metallurgy – 07 – C

Patent

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260/528.4, 260/5

C07C 53/124 (2006.01) B01J 31/28 (2006.01) C07C 51/14 (2006.01)

Patent

CA 1195340

ABSTRACT A process for the selective hydrocarboxylation of propylene to produce predominantly isobutyric acid in the liquid phase is provided. The reaction of propylene, carbon monoxide and water is effected at a temperature of about 75°C to about 150°C and at a pressure of about 250 psi to about 5000 psi in the presence of a suitable solvent and a catalyst comprising palladium or a palladium compound, a phosphoamine promoter ligand compound and a hydrogen halide.

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