Selective hydrodesulfurization and mercaptan decomposition...

C - Chemistry – Metallurgy – 10 – G

Patent

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C10G 45/02 (2006.01) C10G 45/08 (2006.01) C10G 45/12 (2006.01) C10G 65/04 (2006.01)

Patent

CA 2593062

A process for the selective hydrodesulfurization of olefinic naphtha streams containing a substantial amount of organically-bound sulfur and olefins. The olefinic naphtha stream is selectively desulfurized in a hydrodesulfurization reaction stage. The hydrodesulfurized effluent stream is conducted to an interstage stripping zone and separated into a stripper lower boiling stream and a stripper higher boiling stream and the stripper higher boiling stream is further processed in a mercaptan destruction reaction stage to reduce the content of mercaptan sulfur in the final product.

L~invention concerne un procédé d~hydrodésulfuration sélective de flux naphta oléfiniques contenant une quantité substantielle de soufre lié organiquement et d~oléfines. Le flux naphta oléfinique est désulfuré de manière sélective lors d~une étape de réaction d~hydrodésulfuration. Le flux drainant hydrodésulfuré est conduit vers une zone de rectification intermédiaire et séparé en des flux d'ébullition inférieur et supérieur du strippeur, le flux d~ébullition supérieur étant en outre traité lors d~une étape réactionnelle de destruction du thiol afin de réduire la teneur en soufre du thiol du produit final.

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