Selective olefin oligomerization

C - Chemistry – Metallurgy – 07 – C

Patent

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C07C 2/06 (2006.01) C07C 2/26 (2006.01) C07C 11/09 (2006.01)

Patent

CA 2310592

A process is provided for the production of a gasoline blending fraction rich in isooctane by the dimerization of isobutylene using tertiary butyl alcohol modifier and isoalkane diluent; advantageously the isobutylene is derived from the dehydration of tertiary butyl alcohol and the isoalkane used as diluent in the dimerization is the product formed by hydrogenation of the oligomerization product.

L'invention concerne un procédé pour la production d'une fraction de mélange pour carburants, riche en isooctane, par la dimérisation d'isobutylène à l'aide d'un modificateur à l'alcool butylique tertiaire et d'un diluant à l'isoalcane; avantageusement l'isobutylène est dérivé de la déshydratation de l'alcool butylique tertiaire et l'isoalcane utilisé comme diluant dans la dimérisation est le produit formé par hydrogénation du produit d'oligomérisation.

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