Selective oxidation of chrysanthemyl alcohol

Details Selective oxidation of chrysanthemyl alcohol Selective oxidation of chrysanthemyl alcohol

C - Chemistry, Metallurgy

07

C

260/518, 260/567

C07C 47/28 (2006.01) C07C 45/38 (2006.01) C07C 51/16 (2006.01) C07C 51/25 (2006.01) C07C 61/04 (2006.01)

Patent

CA 1059531

ABSTRACT Chrysanthemyl alcohol is selectively oxidized to the corresponding aldehyde by contact with oxygen-containing gas in the presence of supported noble metal catalyst composed of platinum on carbon. The obtained aldehyde may be further con- verted to chrysanthemic acid by oxidation with a solid inorganic oxidizing agent such as silver oxide in excess of stoichiometric quantity, or by reaction with a catalytic amount of oxidation promoting catalyst such as silver oxide in the presence of cupric oxide and molecular oxygen.

256750

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