Selective surface dealumination of zeolites and use of the...

C - Chemistry – Metallurgy – 07 – D

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C07D 233/10 (2006.01) B01J 29/00 (2006.01) B01J 29/40 (2006.01) B01J 29/65 (2006.01) B01J 29/70 (2006.01) C07D 201/04 (2006.01) C01B 33/34 (1990.01)

Patent

CA 2094947

A process for the selective surface dealumination of a zeolite having a Constraint Index greater than 1 comprising contacting the zeolite with dicarboxylic acid, such as oxalic acid. The resultant surface-dealuminated zeolite exhibits improved selectivity for the conversion of cyclohexanone oxime to epsilon caprolactam.

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