Selectively separating oxalic, tartaric glyoxylic and...

C - Chemistry – Metallurgy – 07 – C

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260/534, 260/533

C07C 55/06 (2006.01) C07C 51/487 (2006.01) C07C 59/153 (2006.01) C07C 59/255 (2006.01)

Patent

CA 1067513

ABSTRACT OF THE DISCLOSURE Mixtures of oxalic, meso tartaric, glyoxylic and erythronic acids derived particularly from the oxidation of cellulose deriv- atives are separated from aqueous solutions in which they are contained and from each other by stepwise precipitation with cal- cium ion at controlled pH. The oxalic acid is precipitated as calcium oxalate at a pH of 0.9 to 2.0; the tartaric acid as cal- cium meso tartrate at a pH of 2.8 to 4.4; and the glyoxylic acid, as calcium glyoxylate at a pH of 4.5 to 5.4. After each preci- pitation the water insoluble precipitate is separated from the aqueous mixture in which it is contained. The relatively sol- uble erythronic acid remains in solution as a free acid, or in the form of its calcium salt.

261560

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