Semipermeable membrane made from a homogeneously miscible...

Details Semipermeable membrane made from a homogeneously miscible... Semipermeable membrane made from a homogeneously miscible...

C - Chemistry, Metallurgy

08

J

18/27

C08J 9/28 (2006.01) B01D 67/00 (2006.01) B01D 71/56 (2006.01)

Patent

CA 2008328

A semipermeable membrane is described which comprises a homogeneously miscible polymer blend of an aromatic polyamide and polyvinylpyrrolidone. The aromatic polyamide is in particular formed of recurrent units of the formula I: (see formula I) wherein E1 and E2 are identical or different and are selected from the groupings (see formula II) -Ar1-, and -Ar1-X-Ar2, where Ar1 and Ar2 are the same or different 1,2-phenylene, 1,3-phenylene or 1,4-phenylene groups which may be substituted by (C1-C6) -alkyl , (C1-C6)-alkoxy, -CF3 or halogen and X denotes a) a direct bond or one of the following divalent groups -O-, -C (CF3)2-, -SO2-, -CO-, -C(R1)2-, with R2 being hydrogen, (C1-C6)-alkyl or fluoroalkyl having from 1 to 4 carbon atoms in the alkyl group or b) -Z-Ar1-Z-, where Z is one of the groups -O- and -C(CH3)2 or c) -O-Ar1-Y-Ar2-O-, where Y has the meaning given under Xa) above. The membrane has pronounced hydrophilic properties and is moreover stable to hydrolyzing agents and oxidants and to the action of heat. It is also resistant to organic solvents and microorganisms and exhibits low adsorption of proteins. A process for producing the membrane and a process for modifying the retention capacity thereof are also described. The membrane is produced by spreading a solution of the homogeneously miscible polymer blend on a planar substrate and precipitating the blend. Retention capacity is modified by heat treatment.

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