Separation and purification of ruthenium

C - Chemistry – Metallurgy – 22 – B

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C22B 3/38 (2006.01) C01G 55/00 (2006.01) C22B 3/26 (2006.01) C22B 3/28 (2006.01) C22B 3/32 (2006.01)

Patent

CA 1101678

ABSTRACT A process for the separation or purification of ruthenium from solutions thereof comprising conversion of the ruthenium to nitrosylruthenium complex with the ruthenium in the Ru+2 oxidation state; conversion of the nitrosylruthenium complex to a nitrosylruthenium chlorocomplex and any other platinum group metals to chlorocomplexes; and the removal of the nitrosylruthenium chlorocomplex from solution using a suitable liquid or resin anion exchanger.

280117

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