Separation and recovery of carbon monoxide and unsaturated...

C - Chemistry – Metallurgy – 01 – B

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23/355, 260/717.

C01B 31/18 (2006.01) C07C 7/152 (2006.01) C07C 7/156 (2006.01)

Patent

CA 1208889

ABSTRACT OF THE DISCLOSURE Carbon monoxide, alkenes, alkynes or mix- tures thereof are removed from feedstreams by a process which comprises contacting the feedstream with a solu- tion of a cuprous fluorinated acetylacetonate in an organic solvent containing stabilizing agent to remove carbon monoxide, alkene, alkyne or mixture thereof by forming a first cuprous complex, decomposing the first cuprous complex whereby stabilizing agent replaces carbon monoxide, alkene,or alkyne in the first cuprous complex to form a second cuprous complex, and separat- ing the displaced component. The formation of the second cuprous complex avoids any deposition of copper metal upon heating.

453164

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