Separation and recovery of copper metal from ammoniacal...

C - Chemistry – Metallurgy – 25 – C

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53/290, 204/68

C25C 1/12 (2006.01) C01G 3/00 (2006.01) C07F 1/08 (2006.01) C22B 3/26 (2006.01) C22B 15/00 (2006.01)

Patent

CA 1103464

Abstract of the Disclosure Copper is recovered from solutions containing cupric ammoniacal complexes by reducing copper in the complexes to the cuprous state and thereafter precipitating the cop- per as cuprous acetylide by passing acetylene through the solution. After the cuprous acetylide is separated from the solution and washed thoroughly, it is reacted with ace- tonitrile and an acid to form acetylene and a cuprous- acetonitrile complex: Cu(CH3CN)?. The solution containing this complex is then flash distilled to remove the aceton- itrile and to disproportionate unstable cuprous ions into copper metal and cupric ions. Following the disproportion- ation, the components are separated and copper metal is col- lected.

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