Silicon substituted zeolite compositions and process for...

C - Chemistry – Metallurgy – 10 – G

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252/13, 196/96

C10G 49/08 (2006.01) B01J 37/02 (2006.01) B01J 29/28 (1980.01)

Patent

CA 1171837

ABSTRACT OF DISCLOSURE Aluminum from AlO4 - tetrahedra of as-synthesized zeolites is extracted and substituted with silicon to form zeolite compositions having higher SiO2/A12O3 molar ratios and exhibiting distinctive chemical and physical properties. The preparative procedure involves contact of the starting zeolite with an aqueous solution of a fluorosilicate salt using controlled proportions and temperature and pH condi- tions which avoid aluminum exeraction without silicon sub- stitution.

392137

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