Silicone polyether copolymers and polyurethane foams...

C - Chemistry – Metallurgy – 08 – G

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400/2005, 403/28

C08G 77/46 (2006.01) C08G 18/00 (2006.01) C08G 65/336 (2006.01) C08J 9/00 (2006.01) C11D 3/37 (2006.01)

Patent

CA 2002340

Novel compositions of silicone/polyether block copolymers are provided which are useful as surfactants in several classes of polyurethane foam production. While conventional copolymers have a polysiloxane backbone with pendant polyethers, the surfactants of the present invention are the reverse with siloxane pendants on a polyether chain. These novel non-hydrolyzable polysiloxane polyoxyalkylene copolymers which are characterized by an "inverted" structure, i.e., polyoxyalkylene backbones with lateral and/or terminally pendant polysiloxanes, represent species that are of a narrow molecular weight and compositional distribution and are free of unreacted polyether or non-modified silicone oil diluent. These surfactants are useful in various urethane foam systems and can also display aqueous wetting properties.

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