Sintered silicon carbide/graphite/carbon composite ceramic...

C - Chemistry – Metallurgy – 04 – B

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C04B 35/56 (2006.01) C04B 35/565 (2006.01)

Patent

CA 1226304

SINTERED SILICON CARBIDE/GRAPHITE/CARBON COMPOSITE CERAMIC BODY HAVING ULTRAFINE GRAIN MICROSTRUCTURE ABSTRACT Sintered silicon carbide/graphite/carbon composite ceramic body having a homogeneous fine grain microstructure with at least 50 percent of its silicon carbide grains having a size not exceeding about 8 microns and an aspect ratio less than about 3, with graphite grains having an average size not exceeding that of the silicon carbide grains microns uniformly dispersed throughout the matrix of silicon carbide and having a density of at least 75 percent of theoretical can be made by firing of a shaped green body having a density of at least about 45 percent of theoretical, the shaped green body containing graphite of fine particle size, a sintering aid selected from the group consisting of aluminum, beryllium or boron or compounds containing any one or more of these or a mixture of any of the foregoing elements or compounds, silicon carbide having a surface area of from about 5 to about 100 square meters/gram and, optionally, a temporary binder at a sintering temperature of from about 1900°C to about 2300°C in an inert atmosphere or vacuum. The process for making such pressureless-sintered composite bodies is relatively undemanding of exact temperature/time control during sintering. Contain embodiments of such composite sintered bodies may electrical-discharge machined.

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