Sio2- and zro2-based ceramic fibers and process for the...

C - Chemistry – Metallurgy – 04 – B

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18/576, 75/1.2

C04B 35/80 (2006.01) C04B 35/622 (2006.01) D01F 9/08 (2006.01)

Patent

CA 2009605

23 SiO2- AND ZrO2-BASED CERAMIC FIBERS AND PROCESS FOR THE PREPARATION THEREOF ABSTRACT The present invention relates to ZrO2- and SiO2- based ceramic fibers in which the weight ratio between SiO2 and ZrO2 is comprised between 99 and 0.7. The tetragonal ZrO2 phase is stable at temperatures comprised between 0 and 1500 °C. The process comprises the preparation of: a solution of Zr(OR1)4, where R1 is an alkyl or aryl, Si(OR2)4, where R2 is alkyl or aryl, an organic solvent and an acid. Vapor-phase water is bubbled in said solution, then the obtained solution is drawn and the fibers thus obtained are heated to obtain the crystallization of ZrO2 and SiO2.

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