Size selective catalysis with ion exchange resins

C - Chemistry – Metallurgy – 08 – F

Patent

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C08F 118/02 (2006.01)

Patent

CA 2608991

A method of preparing oligomeric compounds from polyfunctional reactants in the presence of heterogeneous catalysts that exhibit size selective characteristics, such that further reaction between first generation products or first generation products and reactants is less favored than between the starting reactants is disclosed. Preparation of oligomeric polyacrylate compounds in a liquid solution using these catalysts is also disclosed comprising reacting X-H acidic Michael donor compounds with unsaturated Michael acceptor compounds containing more than one unsaturated group .

L'invention concerne une méthode de préparation de composés oligomères à partir de réactifs polyfonctionnels, en présence de catalyseurs hétérogènes présentant des caractéristiques de sélection de taille, de sorte que la réaction entre des premiers produits de génération, ou des premiers produits et des premiers réactifs de génération, est moins prisée qu'une réaction entre les réactifs de départ. La préparation de composés polyacrylate oligomères dans une solution liquide, au moyen de ces catalyseurs, est également décrite. Cette préparation consiste à faire réagir des composés donneurs de Michael acides X-H avec des composés accepteurs de Michael non saturés contenant au moins deux groupes non saturés.

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