Skeletal isomerization of n-pentenes

C - Chemistry – Metallurgy – 07 – C

Patent

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C07C 11/10 (2006.01) C07C 5/27 (2006.01)

Patent

CA 2160673

A process for converting linear C5 olefins in the presence of contaminants C5 diolefins to corresponding iso-olefins of the same carbon number comprises contacting a linear C5 olefin-containing organic feedstock in the presence hydrogen with a catalyst comprising material having the structure of ZSM-35 under conditions including a temperature of 100 and 750 °C, a weight hourly space velocity (WHSV) based on linear C5 olefins in said feedstock between 0.1 and 500 WHSV, and C5 linear olefin partial pressure of 2 to 2000 kPa.

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