Small format, high current density flat plate rechargeable...

H - Electricity – 01 – M

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H01M 10/24 (2006.01) C25B 11/16 (2006.01) H01M 4/24 (2006.01) H01M 4/26 (2006.01)

Patent

CA 2389907

An improved flat plate rechargeable alkaline manganese dioxide-zinc cell comprising a paste-like cathode applied to a first metal based current collector; a mercury- free paste-like anode applied to a second metal based current collector, a separator, and an aqueous alkaline electrolyte. The paste-like cathode comprises active electrolytic manganese dioxide, active electrolytic manganese dioxide, 2-15% by wt of at least one of graphite and carbon black, 2-5% by wt of a polymeric binding agent. 1% or less by wt of electrolyte absorbing agent, 1-15% by wt of a barium compound, and 0.01-10% by wt hydrogen recombination catalyst. The paste like anode comprises a zinc active material, 25-50% by wt of an aqueous electrolyte, 0.5-5.0% by wt thickening agent, 0-5% by wt of electrolyte absorbing agent, and 0-20% by wt of solid zinc oxide. A method of forming paste-like cathodes and anodes for flat plate electrodes is also provided.

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