Soft and tough radiation-curable coatings for fiber optic...

G - Physics – 03 – C

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117/183, 400/505

G03C 1/72 (2006.01) C09D 3/48 (1985.01) C03C 25/02 (1985.01)

Patent

CA 1192330

ABSTRACT A radiation-curable liquid coating composition which cures on radiation exposure to form a soft and tough coating and which is adapted for coating optical fiber is disclosed. This composition comprises a polyurethane, polyamide or polyurea oligomer having (1) a molecular weight in the range of about 2000 to about 8000; (2) amide, urea or urethane groups in an amount of one such group for every 300 to 900 units of weight; and (3) polyalkylene polyether, polyalkylene polysulfide or polyalkylene polyester groups in which the alkylene moiety contains 2-6 carbon atoms. The polyether, poly- sulfide or polyester constitutes about 40% to about 90% by weight of the oligomer, and each end of the oligomer is terminated with a monoethylenically unsatu- rated addition polymerizable group. From 20% to 50% of the weight of the composition is a radiation-curable monoethylenically unsaturated monomer having a Tg below about 10°C., and from 2% to 20% of the composition is a monoethylenically unsaturated monomer having a strong capacity for hydrogen bonding, such as vinyl pyrrolidone.

402848

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