Solar cells incorporating light harvesting arrays

H - Electricity – 01 – L

Patent

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Details

H01L 31/0256 (2006.01) H01L 27/142 (2006.01) H01L 29/12 (2006.01) H01L 31/00 (2006.01) H01L 31/0248 (2006.01) H01L 31/04 (2006.01) H01M 14/00 (2006.01)

Patent

CA 2416778

A solar cell incorporates a light harvesting array that comprises: (a) a first substrate comprising a first electrode; and (b) a layer of light harvesting rods electrically coupled to the first electrode, each of the light harvesting rods comprising a polymer of Formula I (I); wherein m is at least 1, and may be from two, three or four to 20 or more; X1 is a charge separation group (and preferably a porphyrinic macrocycle, which may be one ligand of a double- decker sandwich compound) having an excited-state of energy equal to or lower than that of X2; and X2 through Xm+1 are chromophores (and again are preferably porphyrinic macrocycles).

L'invention concerne une cellule solaire comportant un réseau collecteur de lumière composé (a) d'un premier substrat présentant une première électrode, et (b) d'une couche de tiges collectrices de lumière électriquement couplée à la première électrode. Chaque tige collectrice de lumière contient un polymère de formule (I) dans laquelle m vaut au moins 1, voire de 2, 3, 4 à 20 ou plus ; X?1¿ est un groupe de séparation de charge (de préférence un macrocycle porphrynique pouvant être un ligand d'un composé sandwich à deux étages) présentant un état énergétique excité inférieur ou égal à celui de X?2¿ ; et, X?2¿ provenant de X?m+1¿ sont des chromophores (de préférence des macrocycles porphryniques également).

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