Solar energy storage materials

C - Chemistry – Metallurgy – 09 – K

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C09K 5/00 (2006.01) C09K 5/16 (2006.01)

Patent

CA 1200372

ABSTRACT This invention relates to a solar energy storage material comprising N,N'-bis(phenylacetyl)indigo dissolved in a polar solvent. Of the indigo derivatives capable of storing the solar energy by the photoisomeriz- ation from trans-isomer to cis-isomer of the molecule, all of the compounds obtained so far had an energy storage capacity of only 30 cal or less per 1 g of the compound and also a high thermal isomerization rate from cis form to trans form in solution. Thus, they cannot be called a solar energy storage material of practical value. In the case of the present invention, on the other hand, when N,N'-bis(phenylacetyl)indigo is dis- solved in a polar solvent such as acetonitrile, it is possible to store about 60 cal of energy per 1 g of N,N'-bis(phenylacetyl)indigo, and the half-life period of isomerization from cis to trans from in acetonitrile at 17°C is 1,264 minutes, which is also a satisfactory value for practical application.

427203

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