Solid compositions containing amine oxide-maleic acid salts

C - Chemistry – Metallurgy – 07 – C

Patent

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Details

C07C 291/04 (2006.01) C07C 57/145 (2006.01) C07C 291/06 (2006.01) C11D 1/75 (2006.01) C11D 3/20 (2006.01)

Patent

CA 2187442

Disclosed are solid, concentrated, amine oxide surfactant compositions containing amine oxide-maleic acid salts. The molar ratio of maleic acid to amine oxide in such salts is about a 1:1. The salts are soluble in water at 25° C at a pH of above the pKa of the amine oxide. Also disclosed is a process for preparing such solid amine oxide surfactant compositions, which process comprises admixing maleic acid and amine oxide surfactants in at least about a 1:1 molar ratio, at a pH of at least about 1 unit less than the pKa of the amine oxide, to thereby form a visible precipitate therein. The precipitate is separated from the mixture, preferably by mechanical means, and dried. The dried precipitate is a maleic acid-amine oxide salt which can be incorporated into cleaning products, especially solid or granular cleaning products, as a solid, concentrated source of amine oxide surfactant.

La présente invention concerne des compositions solides, concentrées d'agents tensioactifs à base d'oxyde aminé, contenant des sels d'oxyde aminé-acide maléique. Dans ces sels, le rapport molaire de l'acide maléique avec l'oxyde aminé est d'environ 1:1. Les sels sont solubles dans l'eau à 25~ C à un pH supérieur au pKa de l'oxyde aminé. L'invention porte aussi sur un procédé de préparation de telles compositions tensio-actives solides à base d'oxyde aminé, qui consiste à mélanger de l'acide maléique et des agents tensio-actifs à base d'oxyde aminé selon un rapport molaire d'au moins 1:1, à un pH inférieur d'au moins 1 unité au pKa de l'oxyde aminé de manière à former dans ce dernier un précipité visible. Le précipité est séparé du mélange, de préférence par des moyens mécaniques, et séché. Le précipité séché est un sel d'acide maléique-oxyde aminé qui peut être incorporé dans des produits de nettoyage, notamment solides ou granulaires, comme agent tensioactif solide concentré à base d'oxyde aminé.

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