Solid phase synthesis of compounds by carbon-carbon bond...

Details Solid phase synthesis of compounds by carbon-carbon bond... Solid phase synthesis of compounds by carbon-carbon bond...

C - Chemistry, Metallurgy

07

B

C07B 37/04 (2006.01) C07B 61/00 (2006.01) C07C 233/65 (2006.01) C07C 235/84 (2006.01) C07C 255/41 (2006.01) C07C 317/44 (2006.01) C07D 231/20 (2006.01) C07D 239/46 (2006.01) C07D 239/60 (2006.01) C07F 9/40 (2006.01)

Patent

CA 2338563

Processes are provided for the Mitsunobu alkylation reaction of carbon-carbon bond formation between a solid support reagent and a reagent in solution. The resulting novel products can be prepared as a combinatorial library by high- throughput, parallel synthesis under robotic automation. Cleaved or support- bound products are useful precursors to biologically active compounds.

La présente invention concerne des procédés faisant intervenir une réaction d'alkylation de type Mitsunobu pour la formation d'une liaison carbone-carbone entre une réactif à support solide et un réactif en solution. Les produits nouveaux qui en résultent peuvent être obtenus sous forme de bibliothèque combinatoire par synthèse parallèle à haut rendement en conditions de robotisation automatisée. Des produits avec ou sans support constituent des précurseurs utiles pour des composés biologiquement actifs.

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