Solubilized anionic polymerization initiators and products...

C - Chemistry – Metallurgy – 08 – F

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C08F 4/48 (2006.01) B60C 1/00 (2006.01) C08C 19/44 (2006.01) C08F 8/00 (2006.01) C08F 8/30 (2006.01) C08F 36/04 (2006.01) C08L 21/00 (2006.01)

Patent

CA 2124144

The present invention is directed toward anionic polymerization initiators which are soluble in acyclic alkane solvents. The initiators include a solubilized lithio amine having the general formula (A)Li(SOL)y. SOL is a solubilizing component and A is an alkyl, dialkyl or cycloalkyl amine radical or a cyclic amine and y is from about 1 to 4. The cyclic amine has an alkylene, oxy- or amino-alkylene group having from about 3 to about 16 methylene groups. The invention is also directed toward polymers and other products made using the initiator, and methods therefor. Further, the invention contemplates a polymer, a polymer composition and products therefrom, which include a functional group from the reaction product of an amine and an organolithium compound. The resulting polymers may be terminated with a terminating, coupling or linking agent, which may provide the polymer wtih a multifunctionality.

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