Soluble polyacetylenic and polyaromatic polymers and method...

Details Soluble polyacetylenic and polyaromatic polymers and method... Soluble polyacetylenic and polyaromatic polymers and method...

C - Chemistry, Metallurgy

08

F

402/371, 402/609

C08F 4/06 (2006.01) C08F 38/00 (2006.01)

Patent

CA 1224897

SOLUBLE POLYACETYLENIC AND POLYAROMATIC POLYMERS AND METHOD OF MAKING THE SAME ABSTRACT OF THE DISCLOSURE A soluble polyene polymer and a method of making the same are disclosed. The polymer is of the class suitable for doping to produce an electrically conductive polymer. The method is generally applicable to acetylenic and aromatic monomers. proven examples of which include acetylene, benzene, anthracene and napthalene. In accordance with the method, the monomer is dissolved in arsenic trifluoride. Arsenic pentafluoride is then introduced into the solution to induce polymerization by what is speculated to be an ionic polymerization reaction. The resulting polymer differs from other polyene polymers in that it is soluble in common organic solvents, and further in that it can be melted without undergoing decomposition, thereby rendering it particularly suitable for processing to form various polymeric articles.

469831

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