Solution and method for scavenging sulphur compounds

B - Operations – Transporting – 01 – D

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B01D 53/14 (2006.01) A61L 9/01 (2006.01) C02F 1/72 (2006.01)

Patent

CA 2471648

There is disclosed herein a solution for removing a sulphur compound or carbon dioxide from a fluid and methods for its use, said solution comprising sulphuric acid, a metal at between about 0.05 to 10 percent by weight, an amine at between about 10 to 80 percent by volume and water. In one aspect, the sulphuric acid is in the form of a chelating agent and in another it is in the form of a derivative of a sulphur-based acidic compound. The sulphur compound may be hydrogen sulphide, carbonyl sulphide or a mercaptan. In one aspect, the method is practiced at temperatures significantly below zero. In another aspect, this invention is an acid/amine solution comprising sulphuric acid, sulphuric acid in the form of a chelating agent, or a derivative of a sulphur-based acidic compound and monoethanolamine. This solution may be used as a source of monoethanolamine.

L'invention concerne une solution destinée à éliminer un composé sulfuré ou du dioxyde de carbone d'un fluide, et des procédés d'utilisation de celle-ci. Ladite solution comprend de l'acide sulphurique, un métal d'environ 0,05 à 10 pour cent en poids, une amine d'environ 10 à 80 pour cent en volume et de l'eau. Dans un aspect, l'acide sulfurique se présente sous forme d'un agent de chélation et dans un autre, sous la forme d'un dérivé d'un composé acide à base de soufre. Le composé sulfuré peut être de l'hydrogène sulfuré, du sulfure de carbonyle ou un mercaptane. Dans un aspect, le procédé est mis en oeuvre à des températures très en dessous de zéro. Dans un autre aspect, l'invention est une solution acide/d'amines comprenant de l'acide sulfurique, de l'acide sulfurique sous forme d'un agent de chélation, ou un dérivé d'un composé acide à base de soufre et une monoéthanolamine. Cette solution peut être utilisée comme source de monoéthanolamine.

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