Solution feed, slurry polymerization process for the...

C - Chemistry – Metallurgy – 08 – F

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C08F 2/06 (2006.01) A61K 6/083 (2006.01) A61K 6/087 (2006.01) C08F 216/18 (2006.01) C08F 222/06 (2006.01)

Patent

CA 2014027

FDN-1731 SOLUTION FEED, SLURRY POLYMERIZATION PROCESS FOR THE PRODUCTION OF COPOLYMERS OF MALEIC ANHYDRIDE AND AN ALKYL VINYL ETHER HAVING PREDETERMINED SPECIFIC VISCOSITIES Abstract What is described herein is a solution feed, slurry precipitation polymerization process for making copolymers of maleic anhydride and an alkyl vinyl ether within a predetermined viscosity range. The process of the invention is characterized by precharging a large excess of the alkyl vinyl ether in a reactor, feeding maleic anhydride dissolved in a minimum amount of an organic solvent into the precharged reactor, and polymerizing the monomers in the presence of a free radical initiator. The copolymer product then appears as a pumpable slurry in the reaction medium. The slurry is discharged from the reactor and the desired copolymer is obtained therefrom as a fine, white powder having specific viscosities in the range of about 1.5-6.0, and preferably about 2.6-3.5.

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