Solution process for the preparation of polymers of...

C - Chemistry – Metallurgy – 08 – F

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402/610, 402/638

C08F 10/02 (2006.01) C08F 4/68 (2006.01) C08F 10/00 (2006.01)

Patent

CA 1220189

ABSTRACT OF THE DISCLOSURE A solution process, and a catalyst therefor, for the preparation of high molecular weight polymers of .alpha.-olefins viz. homopolymers of ethylene and copolymers of ethylene and C3-C12 .alpha.-olefins, is disclosed. The process is operated under solution polymerization conditions at 105- 320°. The catalyst is obtained from titanium tetrahalides, vanadium oxytrihalides and organoaluminum compounds, in which an admixture of catalyst components is heat-treated at 150- 320°C, and activated with an alkyl siloxalane. The catalyst has good activity and the polymer obtained has improved colour.

458019

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