Solvent compositions for removing petroleum residue from a...

C - Chemistry – Metallurgy – 11 – D

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C11D 7/26 (2006.01) C11D 7/50 (2006.01)

Patent

CA 2551855

Water-soluble solvent compositions, including from about 10% to about 60% by weight of an aromatic ester; from about 30% to about 60% by weight of an aliphatic ester; from 0% to about 15% by weight of a co-solvent; from 0% to about 20% of one of a cyclic terpene and a terpenoid; from 0% to about 1 % by weight of an odor-masking agent; and from 0% to about 20% by weight of a nonionic surfactant, for removing petroleum residue from a substrate, and methods of use thereof. The composition can further comprise water. The composition also can comprise an aqueous solution. The method for removing petroleum residue from a substrate can further comprise recycling the solvent composition by using a countercurrent separation column charged with compressed ammonia and/or carbon dioxide and a spinning band distillation column to separate the solvent composition from the petroleum residue.

L'invention concerne des compositions de solvant solubles dans l'eau, qui comprennent d'environ 10 % à environ 60 % en poids d'un ester aromatique ; d'environ 30 % à environ 60 % en poids d'un ester aliphatique ; d'environ 0 % à environ 15 % en poids d'un cosolvant ; d'environ 0 % à environ 20 % d'un terpène et/ou d'un terpénoïde cycliques ; d'environ 0 % à environ 1 % en poids d'un agent de masquage d'odeur ; et d'environ 0 % à environ 20 % en poids d'un tensioactif non ionique, lesdites compositions permettant d'éliminer un résidu pétrolier d'un substrat. L'invention concerne aussi des procédés d'utilisation de ces compositions. La composition peut en outre comprendre de l'eau. Elle peut aussi comprendre une solution aqueuse. Le procédé permettant d'éliminer un résidu pétrolier d'un substrat comporte l'étape consistant à : recycler la composition de solvant au moyen d'une colonne de séparation à contre-courant chargée d'ammoniac et/ou de dioxyde de carbone comprimé(s), et d'une colonne de distillation à bande rotative pour séparer la composition de solvant du résidu pétrolier.

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