Specific binding assay employing an enzyme cleavable...

C - Chemistry – Metallurgy – 07 – H

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C07H 17/06 (2006.01) C07D 209/48 (2006.01) C07D 233/78 (2006.01) C07H 17/075 (2006.01) C07H 21/00 (2006.01) G01N 33/533 (2006.01) G01N 33/535 (2006.01)

Patent

CA 1133474

ABSTRACT OF THE DISCLOSURE An improved specific binding assay method and reagent for determining a ligand in a liquid medium employing, as an enzyme-cleavable substrate label, a residue having the formula: G-D-R wherein G is a glycone, D is a dye indicator moiety, and R is a linking group through which the label residue is covalently bound to a binding component of a conventional binding assay system, such as the ligand, an analog thereof, or a specific binding partner thereof. The monitored characteristic of the label is the release of a detectable product, usually a fluorogen or chromogen, upon enzymatic cleavage of the glyco- sidic linkage between the glycone and the dye indicator moiety. The assay method may follow a homogeneous or hetero- geneous format. The preferred glycone is a .beta.-galactosyl group and the preferred dye indicator moiety is an umbelliferone residue. The improved assay is particularly suited to the determination of haptens such as drugs, particularly the aminoglycoside antibiotics.

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