Stabilization of amine alanes

C - Chemistry – Metallurgy – 07 – F

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260/425.1

C07F 5/06 (2006.01) C01B 6/06 (2006.01) C01B 6/24 (2006.01)

Patent

CA 1276939

ABSTRACT OF DISCLOSURE Amine alane decomposition can be reduced or eliminated by using an effective amount of a decomposition retarding agent selected from the class consisting of oxygen, carbon monoxide, nitrogen oxides, and alkyl nitrites. First, this invention can be used to treat an amine alane-containing mixture that also contains a titanium species. Second, this invention can be used to passivate titanium present in a NaAlH4 preparation that is to be used for preparing an amine alane. Third, this invention can be used to passivate titanium when the amine alane is being produced. This invention can also be extended to retardation of amine alane decomposition which occurs when titanium is absent or substantially absent.

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