Stabilization of polyphosphazenes

C - Chemistry – Metallurgy – 08 – K

Patent

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23/59, 400/8201,

C08K 5/34 (2006.01) C08K 3/22 (2006.01) C08K 5/3432 (2006.01)

Patent

CA 1098281

ABSTRACT OF THE DISCLOSURE A poly(phosphazene) represented by the general formula: Image wherein n represents an integer from 20 up to about 50,000 and X an X1 each represent a monovalent substituent selected from the groups consisting of alkoxy, substituted alkoxy, aryloxy, substituted aryloxy, hydroxy, and amino, and X and X1 are randomly distributed along the -P=N- backbone, is stabi- lized against thermal aging by the incorporation of a stabilizer consisting of (1) an organic compound compatible with the poly(phosphazene) and present in an amount sufficient to sta- bilize the poly(phosphazene) against thermal degradation up to temperatures of about 500°F, the organic compound being selec- ted from the group consisting of substituted picolinamides and substituted thiopicolonamides wherein the substituents are selected from the group consisting of hydroxy, alkyl, aryl, alkoxy and halogen, and (2) a basic oxide selected from the group consisting of MgO and ZnO and present in an amount sufficient to render the picolinamide effective as a stabilizer. The combination of such additives acts synergistically in inhibiting thermal degradation of the poly(phosphazene).

298924

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