Stacked bed catalyst system for deep hydrosulfurization

C - Chemistry – Metallurgy – 10 – G

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Details

C10G 65/04 (2006.01) B01J 27/045 (2006.01) C10G 45/04 (2006.01)

Patent

CA 2190392

The present invention relates to a method of removing sulfur from a hydrotreating process stream comprising contacting a sulfur containing feedstock with a stacked bed catalyst system comprising a first catalyst bed comprising hydrodesulfurization catalysts followed by a second catalyst bed comprising ruthenium sulfide having a surface area of at least about 30 m2/g and wherein said hydrodesulfurization process is conducted at a temperature of about 150 ~C to about 400 ~C and a pressure of about 50 psig (344.74 kPa) to about 2500 psig (17236.89 kPa).

Procédé destiné à éliminer le soufre d'un flux soumis au processus d'hydrotraitement, qui consiste à mettre en contact une matière de départ contenant du soufre avec un système de catalyseur à lits empilés comprenant un premier lit de catalyseur qui contient des catalyseurs d'hydrodésulfuration, suivi par un deuxième lit de catalyseur qui contient du sulfure de ruthénium ayant une aire de surface d'au moins 30m?2¿/g environ. Dans ledit procédé, le processus d'hydrodésulfuration est mené à une température située entre environ 150 ~C et environ 400 ~C et à une pression située entre environ 50 psig (344,74 kPa) et environ 2.500 psig (17.236,89 kPa).

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