Staged purification of contaminated propylene oxide

C - Chemistry – Metallurgy – 07 – D

Patent

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C07D 303/04 (2006.01) B01D 3/40 (2006.01) C07D 301/32 (2006.01)

Patent

CA 2134319

STAGED PURIFICATION OF CONTAMINATED PROPYLENE OXIDE (Docket No. 81,173-F) ABSTRACT OF THE DISCLOSURE Contaminants are removed from impure propylene oxide by fractionating in a first column to remove overhead essentially all of the pentenes and pentanes and most of the oxygen- containing impurities to provide a partially purified first propylene oxide bottoms fraction, extractively distilling the first bottoms fraction in a second extractive column using a C2 to C6 alkylene glycol extractive distillation agent to form a second overhead fraction comprising propylene oxide, hex- enes, hexanes, water, residual quantities of pentenes and pentanes and oxygen-containing impurities, extractively distilling the second overhead fraction in a third column using a C6 to C10 alkane hydrocarbon extractive distillation agent to form a third bottoms fraction comprising the extrac- tive distillation agent, propylene oxide, hexenes, hexanes, residual quantities of pentenes and pentanes and water, and extractively distilling said third bottoms fraction in a fourth column using a C6 to C10 alkane hydrocarbon extractive distillation agent to form a fourth overhead fraction consist- ing essentially of propylene oxide.

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