Steel products having superior weathering, method of...

C - Chemistry – Metallurgy – 23 – C

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C23C 22/00 (2006.01) C23C 8/14 (2006.01) C23C 8/18 (2006.01)

Patent

CA 2256798

The invention provides a steel product having superior weathering which is coated with a rust layer containing 50 or more weight % of non-crystalline rust, a method of producing the steel product, and a method of forming weathering protective rust on a material surface of the steel product. A material of a steel product is placed in an atmosphere in which the dew point is kept constant and the temperature of the steel product material is repeatedly varied between a temperature range of 5°C or more higher than the dew point and a temperature range of 5°C or more lower than the dew point. Weathering protective rust is thereby formed on the material surface of the steel product and a steel product having superior weathering is obtained. Preferably, the atmosphere contains 15 to 50 volume % of oxygen gas, and the temperature of the steel product is varied at a rising rate of 0.1 to 2°C/minute and a lowering rate of 0.01 to 2°C/minute. Alternatively, a desired steel product can also be obtained by placing a material of the steel product in an atmosphere containing 15 to 50 volume % of oxygen gas, keeping constant the dew point in the atmosphere, and keeping the temperature of the steel product material in the atmosphere at a certain value in a temperature range between a temperature 5°C lower than the dew point and a temperature 20°C lower than the dew point; or by placing a material of the steel product in an atmosphere containing 15 to 50 volume % of oxygen gas, and forming and keeping a water film with a thickness not more than 500 µm but not less than 50 µm on a material surface of the steel product.

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