Stereoregular acrylonitrile polymer and composition...

C - Chemistry – Metallurgy – 08 – F

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402/489, 400/921

C08F 20/44 (2006.01) C08L 33/20 (2006.01) D01F 6/18 (2006.01)

Patent

CA 2016083

- 25 - STEREOREGULAR ACRYLONITRILE POLYMER AND COMPOSITION COMPRISING SAME ABSTRACT OF THE DISCLOSURE Disclosed is a linear acrylonitrile polymer having a viscosity average molecular weight of at least 50,000, which has a stereoregularity such that the polymer satisfies requirements of I > 0.4 and (I + 3S) > 0.95, wherein I represents the fraction of the isotactic triad and S represents the fraction of the syndiotactic triad. A shaped article is made from a composition comprised of the linear acrylonitrile polymer and a solvent or plasticizer which is selected from a protonic acid and an aqueous solution thereof, an aqueous inorganic salt solution, and a mixture of an organic solvent and an inorganic salt. The fiber made therefrom has an enhanced drawability.

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