Storage stable oligourethanes which are self cross- linking...

C - Chemistry – Metallurgy – 08 – K

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117/113, 402/131

C08K 5/16 (2006.01) C08G 18/10 (2006.01) C08G 18/38 (2006.01) C08G 18/80 (2006.01)

Patent

CA 1234828

Mo-2646 LeA 22,876 STORAGE STABLE OLIGOURETHANES WHICH ARE SELF CROSS-LINKING AT ELEVATED TEMPERATURE OR CAN BE CROSS-LINKED WITH ORGANIC POLYISOCYANATES, A PROCESS FOR THEIR PREPARATION AND THEIR USE AS BINDERS OR BINDER COMPONENTS ABSTRACT OF THE DISCLOSURE The present invention is directed to oligo- urethanes which are stable in storage at room temperature and either self cross-linking at elevated temperatures or capable of being cross-linked with organic polyisocyanates which may have at least partially masked isocyanate groups, a) containing about 0.1 to 3% by weight of tertiary amine nitrogen atoms in the form of structural units corresponding to the following formula attached through urethane groups either in end positions and/or within the molecule: Image wherein R1 represents hydrogen or an alkyl group having 1 to 4 carbon atoms, R2 represents -C?N, -CO-NH2-, -CO-NHR3, -CO-NR? or -COOR3 and R3 represents a monovalent hydrocarbon group optionally carrying inert substituents, b) up to about 15% by weight of isocyanate groups and c) up to about 15% by weight of masked isocyanate groups. The present invention is additionally directed to a process for the preparation of these oligo- urethanes and to their use for coating heat resistant substrates, optionally in admixture with organic polyisocyanates which may have masked isocyanate groups.

474414

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