Styrene-butadiene rubber for truck tires

C - Chemistry – Metallurgy – 08 – F

Patent

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Details

C08F 236/10 (2006.01) B60C 1/00 (2006.01) B60C 11/00 (2006.01) C08F 236/06 (2006.01) C08L 7/00 (2006.01) C08L 9/06 (2006.01)

Patent

CA 2088846

Abstract of the Disclosure STYRENE-BUTADIENE RUBBER FOR TRUCK TIRES The subject invention discloses a styrene- butadiene rubber (SBR) which is particularly valuable for use in making truck tire treads, said rubber being comprised of repeat units which are derived from about 10 weight percent to about 20 weight percent styrene and from about 80 weight percent to about 90 weight percent 1,3-butadiene, wherein the repeat units derived from styrene and 1,3-butadiene have a sequence distribution wherein at least about 55% of the styrene repeat units are in blocks of only one styrene repeat unit, wherein at least about 75% of the styrene repeat units are in blocks of 1 or 2 repeat units, and wherein at least about 5% of the styrene repeat units are in blocks of more than 8 repeat units, wherein from about 32% to about 40% of the repeat units derived from the 1,3-butadiene are of the cis- microstructure, wherein from about 50% to about 60% of the repeat units derived from the 1,3-butadiene are of the trans-microstructure, wherein from about 6% to about 15% of the repeat units derived from the 1,3- butadiene are of the vinyl-microstructure, wherein the rubber has a glass transition temperature which is within the range of about -85°C to about -70°C, wherein the rubber has a number average molecular weight which is within the range of about 150,000 to about 400,000, wherein the rubber has a weight average molecular weight of about 300,000 to about 800,000, and wherein the rubber has an inhomogeneity which is within the range of about 0.5 to about 1.5.

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