Substituted cobalt oxide spinels, electrodes for oxygen...

C - Chemistry – Metallurgy – 25 – B

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204/195.1

C25B 11/04 (2006.01)

Patent

CA 1198087

ABSTRACT OF THE INVENTION Electroconductive substrates are coated with an interface layer and then with cobalt oxide spinels conforming substantially to the empirical formula MxZyCo3-(x+y)O4 where M represents at least one metal from the Groups IB, IIA, IIB, where Z represents at least one metal from Group IA where x is greater than zero but not greater than 1, where y is equal to or greater than zero but not greater that 0.5, and where (x plus 2y) is greater that zero but not greater than 1. The composites are prepared by thermally oxidizing metal oxide precursors in-situ on the sub- strate, including, optionally, modifier metal oxide materials as a separate dispersed phase in the contiguous spinel structure. The interface layer comprises at least on oxide of Pb, Sn, Sb, Al, In, or mixtures of these.

459820

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